Lowicryl HM23 - Monomer G

1. Identification

Product Identifiers

Product Name

Lowicryl HM23 - Monomer G

Other Names

Not available.

Product Number(s)

14360G, EMS14360

CAS Number

Not available.

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Hazard-determining components of labelling:
• eythl methacrylate
• N-BUTYL METHACRYLATE, MONOMER
• Highly flammable liquid and vapour.
• Causes skin irritation.
• Causes serious eye irritation.
• May cause an allergic skin reaction.
• May cause respiratory irritation.

Precautionary Statement(s)

• Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
• Ground/bond container and receiving equipment.
• Use explosion-proof electrical/ventilating/lighting/equipment.
• Use only non-sparking tools.
• Take precautionary measures against static discharge.
• Avoid breathing dust/fume/gas/mist/vapours/spray.
• Wash thoroughly after handling.
• Use only outdoors or in a well-ventilated area.
• Contaminated work clothing must not be allowed out of the workplace.
• Wear protective gloves/protective clothing/eye protection/face protection.

Primary route(s) of entry

Human Health

Inhalation

Remove person to fresh air and keep comfortable for breathing.

Ingestion

Not available

Eyes

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison centre/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.

Skin

(Or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

If symptoms persist consult doctor.

Inhalation

• Supply fresh air and to be sure call for a doctor.
• In case of unconsciousness place patient stably in side position for transportation

Skin Contact

Immediately wash with water and soap and rinse thoroughly.

Eye Contact

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Other Information

No further relevant information available.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

HAZCHEM

No further relevant information available.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental precautions

• Dilute with plenty of water.
• Do not allow to enter sewers/surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
• Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Prevent formation of aerosols.
• Keep ignition sources away - Do not smoke.
• Protect from heat.
• Protect against electrostatic charges.

Conditions for safe storage

• Store in a cool location.
• Keep receptacle tightly sealed.
• Store in cool, dry conditions in well sealed receptacles.
• Protect from heat and direct sunlight.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.
• Avoid contact with the eyes and skin.

Personal protective equipment

Eye and face protection

Tightly sealed goggles.

Skin protection

The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection

Not available.

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.

9. Physical and Chemical Properties

General information

Appearance

Colourless liquid.

Odour

Uncharacteristic.

pH

Not determined

Vapour Pressure

21.3hPa

Density

0.9g/cm³

Boiling Point

118.9°C

Melting Point

-75°C

Solubility

Fully miscible

Specific Gravity of Density

Not available.

Flash Point

17.8°C

Flammable (Explosive) Limits

Not determined

Ignition Temperature

392.8°C

Formula

Not available.

10. Stability and Reactivity

Reactivity

No further relevant information available.

Chemical stability

No decomposition if used according to specifications.

Possibility of hazardous reactions

No dangerous reactions known.

Conditions to avoid

No further relevant information available.

Incompatible materials

No further relevant information available.

11. Toxicological Information

Acute effects

• 97-63-2 ethyl methacrylate
• Oral LD50 14800 mg/kg (rat)

Eye contact

Irritating effect.

Skin contact

Irritant to skin and mucous membranes. Sensitization possible through skin contact.

Ingestion

Not available.

Inhalation

Not available.

Toxicity and irritation

Irritant

12. Ecological Information

Ecotoxicity

No further relevant information available.

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Other adverse effects

• Water hazard class 1: slightly hazardous for water.
• Do not allow undiluted product or large quantities or it to reach ground water, water course or sewage system.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

No further relevant information available.

UN Number

UN3272

Proper shipping name

3272 ESTERS, N.O.S. (ETHYL METHACRYLATE, STABILIZED, n-BUTYL METHACRYLATE, STABALIZED)

Transport hazard class

Class 3 Flammable liquids

Packing group

II

Environmental hazard

Not applicable.

Special precautions for users

• Warning: Flammable liquids
• Hazard identification number (Kemler code): 33
• EMS Number: F-E,S-D
• Stowage Category: B

Additional information

• DOT
• Quantity limitations:
• On passenger aircraft/rail: 5L
• On Cargo aircraft only: 50L
• ADR
• Excepted quantities (EQ) Code: E2
• Maximum net quantity per inner packaging: 30mL
• Maximum net quantity per outer packaging: 500mL
• IMDG
• Limited quantities (LQ) 1L
• Excepted quantities (EQ) Code: E2
• Maximum net quantity per inner packaging: 30mL
• Maximum net quantity per outer packaging: 500ml

15. Regulatory Information

Poisons Schedule Number

None of the ingredients is listed.

Other Information

A Chemical Safety Assessment has not been carried out.

16. Other Information

SDS preparation date

29 November 2024

Comments

This information is based on or present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.