Safety Data Sheets / Ethyl Alcohol, Denatured

Safety Data Sheet

Ethyl Alcohol, Denatured

Version 1Last reviewed 27 March 2023Catalogue: 15050, 15051, EMS15050, EMS15051

1. Identification

Product Identifiers

Product Name: Ethyl Alcohol, Denatured
Other Names: Not available.
Product Number(s): 15050, 15051, EMS15050, EMS15051
CAS Number: 64-17-5

Recommended use of the chemical and restriction on use

Laboratory chemicals

Company Details

ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia
(07) 4773 9444
pst@proscitech.com
proscitech.com.au

Emergency Contact Details

ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia
(07) 4773 9444
pst@proscitech.com
proscitech.com.au

2. Hazards Identification

Classification of the substance or mixture

GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS08 Health hazard
Carc. 1A H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT SE 2 H371 May cause damage to the central nervous system and the visual organs.

Label Elements

Signal Words: None
Hazard Statement(s): Hazard-determining components of labelling:
Ethyl alcohol
Methyl Alcohol
Highly flammable liquid and vapour.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause damage to the central nervous system and the visual organs.
Precautionary Statement(s): Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.

Primary route(s) of entry

Not available.

Human Health

Inhalation: If exposed or concerned: Get medical advice/attention.
Ingestion: If exposed or concerned: Get medical advice/attention.
Eyes: If exposed or concerned: Get medical advice/attention.
Skin: (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. If exposed or concerned: Get medical advice/attention.

Environment

In case of fire: Use for extinction: CO₂, powder or water spray.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

3. Composition / Information on Ingredients

Name	CAS No.	Content (w/w)	Classification
Ethyl alcohol	64-17-5	>50-≤100%	Not Available
Methyl Alcohol	67-56-1	>2.5-≤10%	Not Available
4-methylpentan-2-one	108-10-1	≤2.5%	Not Available
n-hexane	110-54-3	≤2.5%	Not Available

4. First Aid Measures

Ingestion: If symptoms persist consult doctor.
Inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact: Generally the product does not irritate the skin.
Eye Contact: Rinse opened eye for several minutes under running water.
Other Information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

5. Firefighting Measures

Suitable extinguishing equipment

Fire: CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM: No further relevant information available.

Special protective equipment and precautions for fire fighters

Mouth respiratory protective device.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Wear protective clothing. Keep unprotected persons away.
Environmental precautions: Dilute with plenty of water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Conditions for safe storage: Store in a cool location.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.

8. Exposure Controls / Personal Protection

Exposure Standards

Material	TWA ppm	TWA mg/m³	STEL ppm	STEL mg/m³
64-17-5 Ethyl alcohol	1000ppm	1880mg/m³
67-56-1 Methyl Alcohol	200ppm	262mg/m³	250ppm	328mg/m³
108-10-1 4-methylpentan-2-one	50ppm	205mg/m³	75ppm	307mg/m³
110-54-3 n-hexane	20ppm	72mg/m³

Engineering controls: Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.

Personal protective equipment

Eye and face protection: Tightly sealed goggles.
Skin protection: Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection: Wear protective clothing.
Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

9. Physical and Chemical Properties

General information

Appearance: Colourless liquid.
Odour: Aromatic
pH: Not determined
Vapour Pressure: 59hPa
Density: 0.7905g/cm³
Boiling Point: 79°C
Melting Point: Undetermined.
Solubility: Fully miscible
Specific Gravity of Density: Not available
Flash Point: 14°C
Flammable (Explosive) Limits: Lower: 3.5 Vol%
Upper: 15 Vol%
Ignition Temperature: 425°C
Formula: Not available.

10. Stability and Reactivity

Reactivity: No further relevant information available.
Chemical stability: No decomposition if used according to specifications.
Possibility of hazardous reactions: No dangerous reactions known.
Conditions to avoid: No further relevant information available.
Incompatible materials: No further relevant information available.

11. Toxicological Information

Acute effects: 67-56-1 Methyl Alcohol
Oral LD50 5628 mg/kg (rat)
Dermal LD50 15800 mg/kg (rabbit)
Eye contact: No irritating effect.
Skin contact: No irritant effect.
Ingestion: Not available
Inhalation: No sensitising effects known.
Toxicity and irritation: Harmful

12. Ecological Information

Ecotoxicity: No further relevant information available.
Persistence and degradability: No further relevant information available.
Bioaccumulative potential: No further relevant information available.
Other adverse effects: Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

13. Disposal Considerations

General information

Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.

14. Transport Information

ADG label required

HAZCHEM: No further relevant information available.
UN Number: UN1170
Proper shipping name: 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
Transport hazard class: Class 3 Flammable liquids.
Packing group: II
Environmental hazard: Not applicable.
Special precautions for users: Warning: Flammable liquids.
Hazard identification number (Kemler code): 33
EMS Number: F-E,S-D
Stowage category: A
Additional information: Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category: 2
Tunnel restriction code: D/E

15. Regulatory Information

Poisons Schedule Number: 67-56-1 Methyl alcohol S5, S6
108-10-1 4-methylpentan-2-one S5
108-88-3 toluene S6
Other Information: A Chemical Safety Assessment has not been carried out.

16. Other Information

SDS preparation date: 27 March 2023
Comments: This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.