Benzoyl Peroxide Paste

1. Identification

Product Identifiers

Product Name

2,4-Dichlorobenzyl Peroxide Paste

Other Names

Ben Perox Paste

Product Number(s)

C037 - COMPONENT

CAS Number

-

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

H242 Heating may cause a fire H317 May cause an allergic skin reactionH319 Causes serious eye irritationH360 May damage fertility or the unborn childH410 Very toxic to aquatic life with long lasting effects.

Precautionary Statement(s)

P201 Obtain special instructions before use P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/Store away from clothing/ combustible materials. P234 Keep only in original container. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response :P308 ± P313 IF exposed or concerned: Get medical advice/ attention. P391 Collect spillage. Storage :P403 ± P235 Store in a well-ventilated place. Keep cool.

Human Health

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician

Eyes

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Skin

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

Do not induce vomiting; immediately make victim drink water (two glasses at most) call for medical help immediately.

Inhalation

• Supply fresh air and to be sure call for a doctor.
• In case of unconsciousness place patient stably in side position for transportation.

Skin Contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye Contact

Rinse opened eye for several minutes under running water. If symptoms persist, Call in ophthalmologist

Other Information

Immediately remove any clothing soiled by the product. In case of irregular breathing or respiratory arrest provide artificial respiration.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

HAZCHEM

Not available.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental precautions

Do not let product enter drains

Methods and materials for containment and clean up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions. Take up carefully. Dispose of properly. Clean up affected area. Avoid generation of dusts.Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling

Ensure good ventilation/exhaustion at the workplace. Work under hood. Do not inhale substance/mixture. Prevent formation of aerosols. Keep away from open flames, hot surfaces and sources of ignition. Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Conditions for safe storage

• Keep locked up or in an area accessible only to qualified or authorised persons. Tightly closed and away from sources of ignition and heat. Observe national regulations.
• Store in a well-ventilated place.
• Protect from sunlight

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• Protect from heat. Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
• Keep respiratory protective device available. DO NOT let product enter drains.

Personal protective equipment

Eye and face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

• Protective gloves
• The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
• Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
• Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation ·
• Material of gloves
• The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
• Penetration time of glove material
• The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection

• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing
• Wash hands before breaks and at the end of work.
• Store protective clothing separately.
• Avoid contact with the eyes.
• Avoid contact with the eyes and skin.

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

9. Physical and Chemical Properties

General information

Appearance

White pasty

Odour

Mild

pH

Not determined

Vapour Pressure

at 20 °C: 23 hPa

Density

1.2025 g/cm³

Boiling Point

100 °C

Melting Point

Undetermined.

Solubility

Not miscible or difficult to mix with water.

Specific Gravity of Density

Not determined

Flash Point

Not applicable.

Flammable (Explosive) Limits

• Lower: 0.1 Vol %
• Upper: 2.0 Vol %

Ignition Temperature

390 °C

Formula

Not available

10. Stability and Reactivity

Reactivity

No further relevant information available

Chemical stability

No decomposition if used according to specifications

Possibility of hazardous reactions

No dangerous reactions known.

Conditions to avoid

No further relevant information available

Incompatible materials

No further relevant information available

11. Toxicological Information

Acute effects

• 84-74-2 dibutyl phthalate
• LD/LC50 values relevant for classification:
• Oral LD50 8000 mg/kg (rat)
• Dermal LD50 20,000 mg/kg (rabbit)

Eye contact

Irritating effect

Skin contact

No irritant effect

Ingestion

No further relevant information available

Inhalation

Sensitisation possible through skin contact

Toxicity and irritation

No further relevant information available

12. Ecological Information

Ecotoxicity

Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Other adverse effects

Not known to be hazardous to water.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

Not available.

UN Number

UN3106

Proper shipping name

ORGANIC PEROXIDE TYPE D, SOLID

Transport hazard class

5.2 ± 1

Packing group

III

Environmental hazard

• No
• Marine pollutant: Yes (DOT)

Special precautions for users

Warning: Organic peroxides

Additional information

• Limited quantities (LQ) 500g
• Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity

15. Regulatory Information

Poisons Schedule Number

S2, S4, S5

Other Information

No further relevant information available

16. Other Information

SDS preparation date

25 July 2024

Comments

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.