Aniline-Alcohol 1% Solution

1. Identification

Product Identifiers

Product Name

Aniline-Alcohol 1% Solution

Other Names

Not available

Product Number(s)

26450-02, EMS26450-02

CAS Number

Not available.

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Hazard-determining components of labelling:
• Ethyl alcohol
• aniline
• Methyl Alcohol
• In contact with water releases flammable gases which may ignite spontaneously.
• Causes serious eye irritation.
• May cause an allergic skin reaction.
• Suspected of causing genetic defects.
• May cause cancer.
• May cause damage to the central nervous system and the visual organs.
• Causes damage to organs through prolonged or repeated exposure.

Precautionary Statement(s)

• Obtain special instructions before use.
• Do not handle until all safety precautions have been read and understood.
• Keep away from any possible contact with water, because of violent reaction and possible flash fire.
• Handle and store contents under inert gas. Protect from moisture.
• Do not breathe dust/fume/gas/mist/vapours/spray.
• Wash thoroughly after handling.
• Do not eat, drink or smoke when using this product.
• Contaminated work clothing should not be allowed out of the workplace.
• Wear protective gloves/protective clothing/eye protection/face protection.

Primary route(s) of entry

Human Health

Inhalation

Not available

Ingestion

Not available.

Eyes

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.

Skin

Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

If symptoms persist consult doctor.

Inhalation

• Supply fresh air and to be sure call for a doctor.
• In case of unconsciousness place patient stably in side position for transportation.

Skin Contact

Immediately wash with water and soap and rinse thoroughly.

Eye Contact

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Other Information

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

Use fire extinguishing methods suitable to surrounding conditions.

HAZCHEM

For safety reasons unsuitable extinguishing agents: Water

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental precautions

• Inform respective authorities in case of seepage into water course or sewage system.
• Dilute with plenty of water.
• Do not allow to enter sewer/surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
• Dispose contaminated material as waste according to item 13.
• Ensure adequate ventilation.
• Do not flush with water or aqueous cleansing agents.

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Prevent formation of aerosols.
• Keep ignition sources away - Do not smoke.

Conditions for safe storage

• Keep container tightly sealed.
• Store in cool, dry conditions in well sealed receptacles.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.
• Avoid contact with the eyes.
• Avoid contact with the eyes and skin.

Personal protective equipment

Eye and face protection

Tightly sealed goggles.

Skin protection

Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection

Wear protective clothing.

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

9. Physical and Chemical Properties

General information

Appearance

Clear liquid

Odour

Alcohol-like

pH

6.5-9

Vapour Pressure

Not determined

Density

Not determined

Boiling Point

100°C

Melting Point

Not determined

Solubility

Fully miscible

Specific Gravity of Density

Not determined

Flash Point

Not applicable

Flammable (Explosive) Limits

Not determined

Ignition Temperature

Spontaneously flammable in air

Formula

Not available

10. Stability and Reactivity

Reactivity

No further relevant information available.

Chemical stability

No decomposition if used according to specifications.

Possibility of hazardous reactions

Contact with water releases flammable gases.

Conditions to avoid

No further relevant information.

Incompatible materials

No further relevant information available.

11. Toxicological Information

Acute effects

• 67-56-1 Methyl Alcohol
• Oral LD50 5628 mg/kg (rat)
• Dermal LD50 15800 mg/kg (rabbit)
• 62-53-3 aniline
• Oral LD50 250 mg/kg (rat)
• Dermal LD50 820 mg/kg (rabbit)
• Inhalative LC50-4h 175 mg/l (mouse)

Eye contact

Irritating effect.

Skin contact

No irritant effect. Sensitisation possible through skin contact.

Ingestion

Not available

Inhalation

Not available

Toxicity and irritation

• Harmful
• Irritant

12. Ecological Information

Ecotoxicity

Harmful to fish.

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Other adverse effects

• Water hazard class 1: slightly hazardous for water.
• Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
• Harmful to aquatic organisms.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

For safety reasons unsuitable extinguishing agents: Water

UN Number

UN2929

Proper shipping name

2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.

Transport hazard class

• Class 6.1 Toxic substances
• Label 6.1/3

Packing group

II

Environmental hazard

Not applicable.

Special precautions for users

Warning: Toxic substances

Additional information

Not available.

15. Regulatory Information

Poisons Schedule Number

• 67-56-1 Methyl Alcohol S5, S6
• 62-53-3 aniline S6

Other Information

A Chemical Safety Assessment has not been carried out.

16. Other Information

SDS preparation date

13 January 2025

Comments

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific features and shall not establish a legally valid contractual relationship.